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Titrations...need urgent help! thanks

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Date Posted: 4/14/2008 10:52:14 PM  Status: Live
Titrations...need urgent help! thanks
Course Textbook Chapter Problem
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Question Details:
Calculate the hydronium ion concentration and the pH at the equivalence point when 75.0 mL of 0.9000 M NH3 is mixed with 45.0 mL of 1.5000 M HCl.
Ka=5.6x10-10
[H3O+]
M
pH

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Date Posted: 5/16/2008 10:21:47 AM  Status: Live
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Response:
  The molarity of NH3 = 0.9M
  The volume of NH3 = 75.0 ml
  The molarity of HCl = 1.5 M
  The volume of HCl = 45.0 ml
  The concentration of NH4+ = 0.9M*75ml / 120ml
                                       C  = 0.5625 M
  Given that
   Ka of NH4+ = 5.6x10-10
   We know that
   [H3O+]= √Ka*C
             = √ 5.6x10-10 * 0.5625
             = 1.775 * 10-5 M
      pH = -log([H3O+]) 
            = - log (1.775 * 10-5 M ) 
            = 4.75



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